The Embassy of the Republic of Moldova to the United Kingdom of Great Britain and Northern Ireland was opened in 2004, in London.
The British Embassy to the Republic of Moldova, based in Chisinau, was opened in 2002.
Ambassadors of the Republic of Moldova to the United Kingdom of Great Britain and Northern Ireland:
- 2023 - present - H.E.Mr. Ruslan Bolbocean
- 2018 - 2022: H.E. Ms Angela Ponomariov
- 2011 - 2016: H.E. Mr Iulian Fruntașu
- 2008 - 2009: H.E. Ms Natalia Solcan
- 2004 - 2008: H.E. Ms Mariana Durleșteanu (first resident ambassador to London)
- 2003 - 2004: H.E. Mr Mihai Popov (residing in Brussels)
- 1999 - 2002: H.E. Mr Ion Căpățînă (residing in Brussels)
- 1995 - 1997: H.E. Mr Tudor Botnaru (residing in Brussels)
Ambassadors of the United Kingdom of Great Britain and Northern Ireland to the Republic of Moldova:
- 2023 – present: H.E. Ms Fern Horine
- 2020 - 2023: H.E. Mr Steven Fisher
- 2016 - 2020: H.E. Ms Lucy Joyce
- 2013 - 2016: H.E. Mr Philip Batson
- 2009 - 2013: H.E. Mr Keith Shannon
- 2006 - 2009: H.E. Mr John Beyer
- 2002 - 2006: H.E. Mr Bernard Whiteside (first resident ambassador to Chisinau)
- 1999 - 2002: H.E. Mr Richard Ralph (residing in Bucharest)
- 1995 - 1999: H.E. Sir Andrew Wood (residing in Moscow)
- 1992 - 1995: H.E. Sir Brian Fall (residing in Moscow)